Marvel Knights: Spider-Man Vol. 1 (2004-2005) #4

Plot

He's got an incredible new pad (you won't believe where), a new job, and -- although he doesn't know it -- a new nemesis who's everything that Peter isn't. But first, Spider-Man's got to deal with a more pressing problem -- a shape-shifting super-villain who's developed a nasty habit... and will do anything to feed it. And wait -- who's that hitting on Mary Jane!?

Collects MARVEL KNIGHTS SPIDER-MAN #13-18.